Exercise plus Solution
–
Quick overview
It is rec
ommended to use this ver
sion only f
or a quick overview of the NMR challenge. All animations of the
P
ow
erP
oint
ver
sion ar
e missing, un
der certain cir
cumst
ances quality deficiencies ma
y also occur
.
The higher quality Po
werP
oint files ar
e freely a
vailable f
or download at an
y time.
3
67
.
91
1.
1
1.
2
1.
3
1.
4
1.
5
1.
6
1.
7
1.
8
1.
9
2.
0
2.
1
2.
2
2.
3
2.
4
1
H
ppm
1.51
4.
5
0
1.00
Inte
-
gral
55
2.80
56
0.23
56
7.79
57
5.50
Hz
27
1.
32
27
8
.
95
28
6.
44
Hz
1
H NMR spectrum
rec
orded
at 250.13
MHz
C
7
H
14
O
2
measur
ed
in
CDCl
3
Deduce
the
s
tructure
!
Y
ou
should
try
to
get
a
unique
solu
tion
usin
g
the
tw
o
dimensional
spectr
a.
9
.
17
28
.
08
28
.
75
79
.
85
17
3.
92
170
160
150
140
130
120
1
10
100
80
70
60
50
40
30
20
ppm
13
C
13
C-{
1
H} NMR spectrum
measured
at 62.9 {250.13}
MHz
~
~
~
20
40
80
100
120
140
160
13
C
2.
4
2.
2
2.
0
1.
6
1.
4
1.
2
ppm
1
H
2.
4
2.
2
2.
0
1.
6
1.
4
1.
2
ppm
1
H
6
8
10
12
14
16
20
22
24
26
28
13
C
H,C
-HSQC @ 250.13/62.9 MHz
H,C
-HMBC @ 250.13/62.9 MHz
Don
‘t
worry
about
the
somewha
t
crow
ded
red
labeled
area
.
Ther
e
is
no
closer
look
necessary
, you
don
‘t
need
this
area.
1.
1
1.
2
1.
3
1.
4
1.
5
1.
6
1.
7
1.
8
1.
9
2.
0
2.
1
2.
2
2.
3
2.
4
1
H
ppm
~
9.
1
7
28
.
08
28
.
7
5
79
.
85
17
3.92
170
160
150
140
130
120
1
10
100
80
70
60
50
40
30
20
ppm
13
C
~
CH
3
C
O
H
3
C
CH
3
C
H
2
C
O
H
3
C
missing
HMBC corr
elation
Solution a
t a glance
As soon as you see the gr
een
f
ootprints on the pr
oblem icon, the
s
tep-
by
-s
t
ep-solution is av
ailable
Contributions
Measurements
Rainer Haeßner
Spectrometer time
TU Munich
Discussions and
native English
language support
n.n.
yet
Compilation
Rainer Haeßner
More e
x
ercises
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