C
O
C
H
2
CH
3
O
H
3
C
3.69
2.35
1.16
50.57
26.61
8.35
173.86
7.59 Hz
O
C
H
2
CH
3
C
H
3
C
O
4.14
1.27
2.06
7.14 Hz
59.57
20.05
13.53
O
C
H
2
CH
3
C
H
3
C
O
4.14
1.27
2.06
20.05
59.57
13.53
169.97
7.14 Hz
B
A
Carbon-carbon
couplings
Practical use
~
~ ~
Which satellite pattern due to carbon-carbon coupling
do we expect for the three types of carbon atoms shown
before?
Apparently the coupling pattern for the carbon atom
marked in mauve is unique and we have to look wether
this pattern is visible in the carbon spectra of isomer A
or isomer B.
–– C –– C –– C ––
no satellites due to carbon-carbon coupling
one doublet due to carbon-carbon coupling
two nested doublets due to carbon-carbon coupling
Due to the use of Schoolery‘s rule we already know the
solution. Let us forget this solution to demonstrate the
use of the carbon-carbon coupling pattern.